Explain why the 2nd Electron aiffinity of Chlorine is Endothermic whilst the first electron affinity is exothermic

With the first electron affinity, the chlorine atom is one electron from a full octet ( and is a neutral species). When you add an electron to the chlorine, the negatively charged electron is electrostatically attracted to the positive charge of the nucleus. This results in the release of heat energy,(exothermic process) In contrast, when you are adding the second electron (2nd electron aiffinity) this time you are adding a negatively charged electron to a negative ion. This results in repulsion, you need to put in energy to overcome the repulsive forces, resulting in the process being endothermic

HC

Related Chemistry A Level answers

All answers ▸

Explain why: a) Fluorine is more electronegative than chlorine b)∆H hydration fluoride is more negative than ∆H hydration chloride


What is a nucleophile and what is an electrophile?


Q1. Two beakers, A and B, each contain 100.0 cm^3 of 0.0125 mol/dm^3 nitric acid. Calculate the pH of the solution formed after 50.0 cm^3 of distilled water are added to beaker A. Give your answer to 2 decimal places.


How can crude oil be used as a source of hydrocarbons?