What factors affect the lattice enthalpy of an ionic solid?

We must remember that negative energies (in any context) generally represent energetically stable configurations and as the energy of a system increases, it will become more unstable.

Firstly, ionic size affects the lattice enthalpy of a ionic crystal. In an ionic crystal, smaller ions can pack more closely together and exert a stronger electrostatic force of attraction on each other, making the compound more stable and the lattice enthalpy more negative. Secondly, as the magnitude of the product of the ionic charges increases, the electrostatic force of attraction will increase in magnitude, again resulting in a more stable lattice and more negative lattice enthalpy.

SD
Answered by Sebastian D. Chemistry tutor

7702 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Q3. A third beaker, C, contains 100.0 cm^3 of 0.0125 mol/dm^3 ethanoic acid ( Ka = 1.74 × 10^−5 mol/dm^3 at 25 ºC). Write an expression for Ka and use it to calculate the pH of the ethanoic acid solution in beaker C.


A 20cm³ sample of lithium hydroxide solution of unknown concentration is neutralised by 12.25cm³ of 0.15mol/dm³ of sulfuric acid. Calculate the concentration of the lithium hydroxide solution.


What's added to Ethanoyl Chloride to make Methyl Ethanoate? Draw out the mechanism for this reaction. Why is this preferred to esterification?


Draw the structure, name the shape and show bond angles of the molecules XeF4 and SbF4-. In your answer explain why each structure is different, despite both having a central atom, surrounded by 4 fluorine atoms.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning