My explanation would depend on the level of understanding of the person but one way would be the following:
We know that a = 2. Substitute the value of "a" in the given equation:
2(2-b)+3(2+b)
We know b = 3. Then substitute the value of "b" in the previous equation:
2(2-3)+3(2+3)
By order of operations, solve the operations inside the parenthesis first:
2(-1)+3(5)
Then we do the multiplications :
-2+15
Finally we complete the operation to get: 13