Why does nuclear radius decrease and first ionisation energy increase across the period?

As we move across the period electrons occupy the same outer electron shell, having roughly the same distance to the nucleus. Moving across the period nuclear charge increases as the number of protons in the nucleus increases, conversly nuclear shielding remains about the same across the row meaning the effective nuclear attraction rises and therefore the nuclear radius also reduces. Because the attraction betweent outer electrons and the nuclear is higher, more energy is required to ionise the atom (remove an electron).

JM

Related Chemistry A Level answers

All answers ▸

How does increasing/decreasing temperature affect the equilibrium position of the following reaction: CuSO4.5H2O(s) ⇌ CuSO4(s) + H2O(l) ?


How does a mass spectrometer work?


How is benzene nitrated?


You added 75cm^3 of 0.5moldm^-3 HCl to impure MgCO2, and some was left unreacted. The unreacted HCl reacted completely with 21.6cm^m of 0.5moldm^-3 NaOH. So what is the percentage purity of the MgCO3 sample?