Predict whether the lattice energy of magnesium oxide, MgO, is more or less exothermic than the lattice energy of magnesium sulfide, MgS. Justify your answer in terms of the sizes and the charges of the ions involved.

To start with, we can clearly see that the difference between MgO and MgS is the anions, we have O(2-) and S(2-). As we know (from looking at the periodic table) O(2-) has a smaller ionic radius, and thereby higher charge density than S(2-), as it has the same charge but packed into a smaller space. As a result, O(2-) will form stronger electrostatic attractions i.e. ionic bonds to Mg(2+) due to the smaller ionic radius and higher charge density, thereby MgO will have a more exothermic lattice enthalpy due to the stronger ionic bonds relative to MgS.

Answered by Huzair A. Chemistry tutor

16724 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Explain why compounds of Fe^2+ are coloured in solution. (4 marks)


Explain the trends in reactivity as you move down group one elements.


What is the rate of a reaction and how can you determine it experimentally?


The shape around the oxygen atom in butan-2-ol is non linear. Predict the shape and angle of the C-O-H bond giving explanations


We're here to help

contact us iconContact usWhatsapp logoMessage us on Whatsapptelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo
Cookie Preferences