Why do first ionisation energies decrease down a group?

Ionisation energy is defined as the energy required to remove an electron from a gaseous atom or ion. As we descend down a periodic group we must think about how the atomic radius. As we descend the group the atomic radius begins to increase. This means that the electrons are increasing in distance from the nucleus of the atom. The protons in the nucleus tend to increase the attraction of the electrons to the nucleus. As such if the electrons are further away from this attraction they are more easily removed from the atom. As such the energy required to remove the electron is less as we descend the group.

JT
Answered by Jonathan T. Chemistry tutor

4349 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

What is the evidence that disproves the Kekule model for benzene?


Explain the decrease in reactivity of Group 2 elements as you go down the periodic table


What is the difference between complete and incomplete combustion of a hydrocarbon?


Why can endothermic reactions occur spontaneously if the entropy change is negative for a cooling process?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning