Draw the structure of chlorine pentafluoride (ClF5) according to the VSEPR theory

The molecule is uncharged, so we can find that chlorine is in its +5 oxidation state. Since there are 5 Cl-F bonds, there are 5 bonding electron pairs around the central Cl atom. We also know that chlorine is in group 7, so it has 7 valence electrons. 5 out of those seven are "tied up" in the Cl-F bonds, thus the remaining two must form a non-bonding electron pair. We have 6 electron pairs (5 bonding and 1 non-bonding) to arrange around the chlorine center - which suggests an octahedral shape. However, since we have one electron pair, the shape of the molecule will be pyramidal.

PS

Related Chemistry A Level answers

All answers ▸

When propanal is reacted with potassium cyanide under weakly acidic conditions the resulting mixture does not rotate plane polarised light. Explain this observation.


Why do elements give off coloured light when heated?


Why is there a difference in mechanism between tertiary halogenoalkanes and primary halogenoalkanes in nucleophilic substitution?


State the element in period 3 that has the highest melting point and explain your answer.