What is hydrogen bonding and why does water have a higher boiling point than methanol?

Hydrogen bonding is an intermolecular interaction between a partially positively charged hydrogen atom on one molecule and a partially negatively charged atom on another molecule. The difference in charge is due to the atom bonded to the hydrogen being more electronegative. Water has two partial positive hydrogens and one partial negatively charged oxygen whereas methanol only has one partial positive hydrogen (with the methyl group being unable to take part in hydrogen bonding). From this, a greater amount of hydrogen bonding can take place between water molecules than between methanol molecules. Thus a greater amount of thermal energy is needed to overcome these intermolecular forces for water, leading to its boiling point being higher than methanol.

MQ
Answered by Max Q. Chemistry tutor

23632 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Explain what is meant by the term "rate of reaction".


Name and explain the three types of isomerism present in organic compounds.


Calculate the pH of the solution formed when 30 cm3 of 0.150 moldm-3 aqueous sulfuric acid is added to 30 cm3 of 0.200 moldm-3 aqueous potassium hydroxide at 25 C.


For the reaction 2H2 + O2 -- 2H2O, how do I give an equation for the equilibrium constant in terms of the concentrations of products and reactants involved?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2025 by IXL Learning