Benzene reacts with Chlorine gas in the presence of iron trichloride to yield hexachlorobenzene. However, when it reacts with fluorine gas, it forms a quinoid product (I would actually draw it for them - no need to know the name). Why the difference?

Fluorine is much more reactive than chlorine, even destroying the aromaticity. This is at the expense of the very strong C-F bonds (good orbital size and energy overlap) that are formed. C-Cl bonds are weaker so even when benzene is "burnt" in chlorine, the aromatic ring stays intact.

RB
Answered by Radu B. Chemistry tutor

2700 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Plan out a 4 step organic synthesis to form N-methyl Butanamide from 1-Bromopropane. Include relevant reagents and conditions for each reaction. Include 1 mechanism for one of the stages.


You have 3.51g of hydrated zinc sulphate. You heat up the zinc sulphate until all the water has evaporated from it. The weight after heating is 1.97g. Find how many H2O molecules per zinc sulphate molecule there are in the hydrated form of it.


Define ferromagnetism, paramagnetism and diamagnetism, and determine whether the following complexes a) AgCl b) [Fe(CN)6]4- c) [Mn(CN)6]4- d) Co(H2O)6Cl2 are ferromagnetic, diamagnetic or paramagnetic giving a full justification for your reasoning.


What is the trend in ionization energy across period 3 in the periodic table?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2025 by IXL Learning