Benzene reacts with Chlorine gas in the presence of iron trichloride to yield hexachlorobenzene. However, when it reacts with fluorine gas, it forms a quinoid product (I would actually draw it for them - no need to know the name). Why the difference?

Fluorine is much more reactive than chlorine, even destroying the aromaticity. This is at the expense of the very strong C-F bonds (good orbital size and energy overlap) that are formed. C-Cl bonds are weaker so even when benzene is "burnt" in chlorine, the aromatic ring stays intact.

RB
Answered by Radu B. Chemistry tutor

2588 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Explain, in terms of frequencies, why solutions of transition metal ions are often coloured.


Explain the geometry and bond angles in a NH3 molecule


Aminoethane can be prepared by a reduction reaction. Identify a starting compound that can be used to prepare aminoethane by reduction, give the necessary reagent and write an equation for the reaction.


What is the difference between exothermic and endothermic?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2025 by IXL Learning