Benzene reacts with Chlorine gas in the presence of iron trichloride to yield hexachlorobenzene. However, when it reacts with fluorine gas, it forms a quinoid product (I would actually draw it for them - no need to know the name). Why the difference?

Fluorine is much more reactive than chlorine, even destroying the aromaticity. This is at the expense of the very strong C-F bonds (good orbital size and energy overlap) that are formed. C-Cl bonds are weaker so even when benzene is "burnt" in chlorine, the aromatic ring stays intact.

Answered by Radu B. Chemistry tutor

2047 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

How can one differentiate between the organic compounds propanal (CH3CH2CHO) and propanone (CH3COCH3)?


Describe how to test for and identify halide ions in a solution.


When both sodium and Hydrochloric acid are added to a test tube, what will be observed?


Describe how you test for an aldehyde or ketone and distinguish between the two.


We're here to help

contact us iconContact usWhatsapp logoMessage us on Whatsapptelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo
Cookie Preferences