Benzene reacts with Chlorine gas in the presence of iron trichloride to yield hexachlorobenzene. However, when it reacts with fluorine gas, it forms a quinoid product (I would actually draw it for them - no need to know the name). Why the difference?

Fluorine is much more reactive than chlorine, even destroying the aromaticity. This is at the expense of the very strong C-F bonds (good orbital size and energy overlap) that are formed. C-Cl bonds are weaker so even when benzene is "burnt" in chlorine, the aromatic ring stays intact.

RB

Related Chemistry A Level answers

All answers ▸

What chemical test can be used to differentiate between alkenes and alkanes. Describe and explain the results.


How could you obtain a carboxylic acid from oxidation of an alcohol and what type of alcohol would be suitable?


Suggest why the concentration of sodium hydroxide in a solution slowly decreases when left open to air


Name and explain briefly the main stages of mass spectroscopy.