Benzene reacts with Chlorine gas in the presence of iron trichloride to yield hexachlorobenzene. However, when it reacts with fluorine gas, it forms a quinoid product (I would actually draw it for them - no need to know the name). Why the difference?

Fluorine is much more reactive than chlorine, even destroying the aromaticity. This is at the expense of the very strong C-F bonds (good orbital size and energy overlap) that are formed. C-Cl bonds are weaker so even when benzene is "burnt" in chlorine, the aromatic ring stays intact.

RB
Answered by Radu B. Chemistry tutor

3224 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Explain Optical Isomerism


Explain the unusually high boiling point of HF


Explain the trends in ionisation energies across the 2nd period of the periodic table?


Draw the full structual diagram of ethyl-ethanoate, labeling relevent bond angles and explain why the molecule has this structure.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning