Benzene reacts with Chlorine gas in the presence of iron trichloride to yield hexachlorobenzene. However, when it reacts with fluorine gas, it forms a quinoid product (I would actually draw it for them - no need to know the name). Why the difference?

Fluorine is much more reactive than chlorine, even destroying the aromaticity. This is at the expense of the very strong C-F bonds (good orbital size and energy overlap) that are formed. C-Cl bonds are weaker so even when benzene is "burnt" in chlorine, the aromatic ring stays intact.

RB

Related Chemistry A Level answers

All answers ▸

a sample of hydrated NiSO4 witha mass of 4.414g is heated to remove all water crystallisation. The resultant mass is 2.287g. How many H2O molecules to each NiSO4 were there in the original sample


What is the difference between London dispersion forces and hydrogen bonds?


Why does ionisation energy of elements generally decrease as you move down a group in the periodic table?


Explain why the element nickel has a high melting point