Benzene reacts with Chlorine gas in the presence of iron trichloride to yield hexachlorobenzene. However, when it reacts with fluorine gas, it forms a quinoid product (I would actually draw it for them - no need to know the name). Why the difference?

Fluorine is much more reactive than chlorine, even destroying the aromaticity. This is at the expense of the very strong C-F bonds (good orbital size and energy overlap) that are formed. C-Cl bonds are weaker so even when benzene is "burnt" in chlorine, the aromatic ring stays intact.

RB
Answered by Radu B. Chemistry tutor

3118 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

When testing for primary, secondary, and teritary alcohols what is the testing reagent and the results of the test?


What chemical test can be used to differentiate between alkenes and alkanes. Describe and explain the results.


Aminoethane can be prepared by a reduction reaction. Identify a starting compound that can be used to prepare aminoethane by reduction, give the necessary reagent and write an equation for the reaction.


You added 75cm^3 of 0.5moldm^-3 HCl to impure MgCO2, and some was left unreacted. The unreacted HCl reacted completely with 21.6cm^m of 0.5moldm^-3 NaOH. So what is the percentage purity of the MgCO3 sample?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning