Benzene reacts with Chlorine gas in the presence of iron trichloride to yield hexachlorobenzene. However, when it reacts with fluorine gas, it forms a quinoid product (I would actually draw it for them - no need to know the name). Why the difference?

Fluorine is much more reactive than chlorine, even destroying the aromaticity. This is at the expense of the very strong C-F bonds (good orbital size and energy overlap) that are formed. C-Cl bonds are weaker so even when benzene is "burnt" in chlorine, the aromatic ring stays intact.

RB
Answered by Radu B. Chemistry tutor

2664 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Explain why atomic radius decreases across a period


A solution of ethanoic acid is made by dissolving 3g of pure liquid propanoic acid in 500cm^3 water. Given the pH of the solution is 2.98, calculate Ka.


A chemist synthesised two solutions A and B, they know one solution is an aldehyde and the other a ketone. Suggest how the chemist could identify which is which and describe any observations they would make


X, a gas, has a mass of 0.270g and is present in a gas syringe with a volume of 105.0cm^3 at 97C and 100kPa. Calculate the Mr of X. (5 marks)


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2025 by IXL Learning