Why, in the bromination of phenols, do you not need an acid catalyst like you do in the bromination of benzene?

Benzene's delocalised π electrons means that it is not very nucleophilic and so cannot polarise a neutral molecule and produce the required electrophile. As a result it require a catalyst to form the electrophile. In phenols, the lone pair from the oxygen delocalises into the π electrons, increasing the electron density in the ring and making it more nucleophilic. This means that it is more able to polarise a molecule and produce an electrophile meaning that a catalyst isn't required.

SA

Related Chemistry A Level answers

All answers ▸

24.5g of CH3CH2CH2Br was reacted with ammonia to form CH3CH2CH2NH2 at a 75.0% yield, calculate the mass of the product formed.


Given the following equilibrium: H2O + H2O <-> H3O+ + OH- and the Kw = 10^-14, determine the concentration of OH- species after the addition of 1 mmol of HCl to 1 L of neutral water.


Why does ice float on water? Use the structure of different states of matter to support your answer.


Describe how to perform a flame test to identify an unknown compound.