What is meant by the term optical isomerism?

Optical isomerism is a form of stereoisomerism (different arrangement of the same atoms in 3D space) which is caused by the presence of a chiral carbon in a molecule. A chiral carbon is a carbon with four different groups attached to it, for example a carbon bonded to a hydrogen atom, carboxylic acid group, amino group and a methyl group is a chiral carbon. The optical isomers of a chiral molecule are known as enantiomers and these enantiomers are non super-imposable mirror images of each other. Enantiomers will rotate plane-polarised light in opposite directions but by an equal amount, so when equal numbers of enantiomers are present in a mixture (known as a racemic mixture), no rotation of plane-polarised light is observed.

Answered by Sophie M. Chemistry tutor

1558 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Explain why the boiling point of PH3 is lower than the boiling point of AsH3


Describe and explain the electrical conductivity of lithium oxide, Li2O, and lithium in their solid and molten states.


Given the following equilibrium: H2O + H2O <-> H3O+ + OH- and the Kw = 10^-14, determine the concentration of OH- species after the addition of 1 mmol of HCl to 1 L of neutral water.


Periodicity shows a fairly smooth increasing trend across a period for ionisation energy. However, between groups 2 & 3 and groups 5 & 6, the trend doesn't appear to be followed. Using your knowledge of chemistry, explain why the trend isn't followed here


We're here to help

contact us iconContact usWhatsapp logoMessage us on Whatsapptelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo
Cookie Preferences