Why can crude oil be separated by fractional distillation?

Crude oil is composed from hydrocarbons of varying chain length. Hydrocarbons with longer chains have higher boiling points due to the increasing strength of intermolecular forces with length, therefore the different components of crude oil have different boiling points.The fractionating column has a temperature gradient and is hotter at the bottom. Crude oil enters the column at the bottom and is heated. Intermolecular forces are broken during boiling and it is easier to break these forces between short chain hydrocarbons as they are weaker. Small hydrocarbons therefore boil more easily then travel up the column as vapour. These short molecules travel up the column the furthest before condensing, so exit nearer the top of the fractionating column. The longest chain hydrocarbons take a lot of energy to boil so condense very quickly as they rise and the temperature decreases, hence exit at the bottom of the fractionating column.

CF
Answered by Charlotte F. Chemistry tutor

6616 Views

See similar Chemistry GCSE tutors

Related Chemistry GCSE answers

All answers ▸

What are covalent and Ionic bonds and how do they differ?


Nitrogen has an atomic number of 7 and mass number of 14, an isotope of nitrogen has a mass number of 17. Explain what an isotope is and state how many electrons, protons and neutrons this isotope has?


What is activation energy?


How do you test for the different halide ions?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2025 by IXL Learning