Why is the boiling point of water significantly greater than that of other group 6 (16) hydrides?

Water exhibits hydrogen bonding between neighbouring molecules, where other group 6 hydrides are held together by much weaker (ca. 10 x) Van Der Waal's forces of attraction. Waters hydrogen bondong ability arises from the presence of a highly electronegative oxygen atom in it's structure. Due to oxygen's propensity to attract negative charge, the shared electron between oxygen and hydrogen in each of the two bonds in water lies closer to the nucleus of oxygen than that of hydrogen. This results in a partially negatively charged oxygen atom and two partially positively charged hydrogen atoms. The partial charges can interact wih the opposite partial charge on a neighbouring molecul, forming a so called 'hydrogen bond.'

JS

Related Chemistry A Level answers

All answers ▸

How do mass spectrometers work?


A chemist mixes together 0.450 mol N2 with 0.450 mol H2 in a sealed container. The mixture is heated and allowed to reach equilibrium. At equilibrium, the mixture contains 0.400 mol N2 and the total pressure is 500 kPa. Calculate Kp.


What is the difference between 'Electrospray Ionisation' and 'Electron Impact' during the ionisation stage in a mass spectrometer?


How do you work out an electron configuration?