Draw an example using a diagram of Carbon, three "Y" substrates and an "L" indicating any leaving group the Sn1 nucleophilic substitution reaction. (3 marks) Which step is fastest (1 mark).

Y3CL -> [Y3C]+ + L-(1 mark)Ligand leaves in first step. Can still show ligand as product anion but no need. Also accept any halide as leaving group.
Step 2 a little harder as not signposted in question. Accept nucleophile, Nuc- or any equivalent.[Y3C]+ +Nuc--> Y3CNuc
The nucleophile attacks the carbocation intermediate. Attack on 2 planes of the compound leading to the same steroisomer produced, but can show the 2 different plane products leading to the same steroisomer product. (2 marks)
The first step of this reaction requires bond breaking (ie endothermic change) to lose the leavin group it is the slower step. By contract a nucleophile will rapidly attack the electrophilic carbon cation to form a new S bond. (1 mark)

Answered by James P. Chemistry tutor

1471 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

i)Explain why first ionisation energy shows a general tendency to increase across a period? ii)Using period 3 as an example, which elements show irregularities in this trend and why?


The reversible reaction of sulfur dioxide and oxygen to form sulfur trioxide is shown below. 2SO2(g) + O2(g) 2SO3(g) An equilibrium mixture contains 2.4mol SO2, 1.2mol O2 and 0.4mol SO3. The total pressure is 250atm. What is the p(SO3)?


Describe a two step reaction route that can convert 1-Butene (CH2CHCH2CH3) into a compound that is more soluble in water. Use mechanisms to aid your answer (HINT: one of the steps involves nucleophilic substitution)


An excess of Lead (II) oxide reacts with 175cm3 of 1.5 mol dm3 nitric acid. Calculate the maximum quantity of lead that can be obtained from this reaction.


We're here to help

contact us iconContact usWhatsapp logoMessage us on Whatsapptelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo
Cookie Preferences