Explain how nucleophilic substitution for a haloalkane actually occurs?

In a haloalkane, not all of the bonds are the same. We have to consider the fact that the halogen atom (for instance a bromine atom) is more electronegative than either carbon or hydrogen atoms, and has a tendency to withdraw electron density towards itself. This makes the C-Br bond polarised. The carbon atom has had electron density removed from itself, and now has a partial positive charge. Thus, it is more susceptible to attack by a species with a high electron density, or a negative charge. Such a species is called a nucleophile. A cyanide ion, for example, has a formal negative charge on the carbon.As like and unlike charges attract, the negative cyanide ion will attack the positive carbon atom, and in doing so will displace the bromide ion. This is nucleophilic substitution.

NK
Answered by Naman K. Chemistry tutor

2303 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Give and explain 2 of the anomalous properties of ice caused by hydrogen bonding


Q2. Calculate the pH of the solution formed after 50.0 cm^3 of 0.0108 mol/dm^3 aqueous sodium hydroxide are added to beaker B. Give your answer to 2 decimal places


When both sodium and Hydrochloric acid are added to a test tube, what will be observed?


How to calculate acidic buffer solution pH, and how do they behave?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning