Predict the boiling points (lowest to highest) of Butan-1-ol, 2-methylpropane and Butane

Butan-1-ol will have the highest boiling point of all 3 as it has Hydrogen bonds acting between molecules. This occurs due to the presence of the electronegative O atom. 2-methylpropane is a branched version of butane, and hence will have the lowest boiling point, as branching of a molecule decreases the surface contact area for London forces to act. This results in weaker and less London forces between molecules, and hence decreases the substances boiling point.

Answered by George W. Chemistry tutor

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