Explain the difference in reactivity between benzene and phenol with bromine?

Phenol reacts with bromine at room temperature with no catalyst as the hydroxyl group activates the ring by donating a pi electron. This donated electron increases the electron density of the ring hence allowing it to polarise a Br2 molecule and create a partially positive Br which can undergo nucleophilic attack.Benzene does not react with bromine on its own and requires a halogen carrier (FeBr3). This is because the ring is not activated and can not polarise bromine on its own. The halogen carrier reacts with bromine to create a bromine cation which can more easily undergo nucleophilic attack and allows a reaction with benzene.

Answered by Reece L. Chemistry tutor

7688 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Calcium nitride contains 81.1% by mass of the metal. Calculate the empirical formula of calcium nitride. Show your working.


What is the difference between empirical and molecular formula?


Define a transition metal


The following equilibrium is set up in a glass syringe. 2(NO2) (brown gas) ‹-› N2O4 (colourless gas) ∆H = -58 kJmol-1. Using le Chatelier's principle, predict and explain how heating up the mixture would affect it's appearance.


We're here to help

contact us iconContact usWhatsapp logoMessage us on Whatsapptelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

© MyTutorWeb Ltd 2013–2025

Terms & Conditions|Privacy Policy
Cookie Preferences