Why does calcium nitrate decompose in a similar way to magnesium nitrate, but require a higher temperature for decomposition?

Calcium ions (Ca2+) have the same charge as magnesium ions (Mg2+) but Ca2+ ions have a larger ionic radius (as ionic radius increases down the group). This means Ca2+ has a lower charge density than Mg2+. With a lower charge density, Ca2+ ions cause less polarisation and distortion of the nitrate (NO3-) electron cloud (and N-O/N=O bonds) than Mg2+ions making decomposition harder. Therefore, calcium nitrate requires more heat to be decomposed.

KA
Answered by Keziah A. Chemistry tutor

6752 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Describe the conditions used in the Haber Process and explain briefly why they are used.


A naturally occurring sample of the element boron has a relative atomic mass of 10.8 In this sample, boron exists as two isotopes. Calculate the percentage abundance of 10B in this naturally occurring sample of boron.


State and explain the conditions for cis/trans isomerism and how this differs from E/Z isomerism.


What is Ionisation Energy and the three factors that affect it? 2)State and explain the general trend in first ionisation energies for the Period 3 elements.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

© MyTutorWeb Ltd 2013–2025

Terms & Conditions|Privacy Policy
Cookie Preferences