Why does calcium nitrate decompose in a similar way to magnesium nitrate, but require a higher temperature for decomposition?

Calcium ions (Ca2+) have the same charge as magnesium ions (Mg2+) but Ca2+ ions have a larger ionic radius (as ionic radius increases down the group). This means Ca2+ has a lower charge density than Mg2+. With a lower charge density, Ca2+ ions cause less polarisation and distortion of the nitrate (NO3-) electron cloud (and N-O/N=O bonds) than Mg2+ions making decomposition harder. Therefore, calcium nitrate requires more heat to be decomposed.

KA
Answered by Keziah A. Chemistry tutor

7740 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Why does the pH of neutral water drop when it is left out in an uncovered container on a worktop for a long period of time?


Why does an ionic compound (e.g. NaCl) conduct electricity when molten or dissolved in water, but not when it is a solid.


Define the term empirical formula. Determine the molecular formula of a compound with the empirical formula C2H4O and a relative molecular mass of 176.0


Explain the shape carbon tetrachloride


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning