Imagine a reaction A for which the values of ΔH and ΔS are both negative. It is known that the absolute value of ΔS is 3 times smaller than the absolute value of ΔH. For what values of T does reaction A occur spontaneously?

We know that a reaction occurs spontaneously when ΔG<0 and that ΔG=ΔH-TΔS. So, we know that the reaction will be spontaneous when ΔH<TΔS.Its is given that ΔH and ΔS are <0 and that |ΔH|=3*|S|. From this we can conclude that the inequation ΔH<TΔS will be true whenT< 3K. We also have to keep in mind that the temperature can never be lower than the absolute zero (0K) and so, the answer is 0K < T < 3K.

AC
Answered by Andre C. Chemistry tutor

1688 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Calculate the pH change when water is added to 25.0 ml of 0.250M NaOH to form a 1.00l solution.


Explain trend in why the ionisation energies increase across the period


2-chloropropanoic acid has a Ka of 1.48E-3. Write an expression for Ka and hence or otherwise, calculate the pH of a 0.35M solution of 2-chloropropanoic acid


What is the difference between stereoisomerism and optical isomerism?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2025 by IXL Learning