To calculate which of titanium chloride or sodium is limiting, convert both into mol so they are directly comparable. You cannot compare in masses because in equations there is a conservation of moles and not mass. Mol = Mass/Mr (Remember most of the time information in the question is valuable).Mass in this equation is in g, so the weight of TiCl4 = 40,000 and weight of sodium = 20,000Mr of TiCL4 = 48 + (35.5 x 4) = 190Mol of TiCl4 = 40,000/190 = 210.52 = 211 mol (round to 3s.f. if not specified)Mol of Na = 20,000/23 = 869.56 = 870 mol1TiCl4 for every 4Na870/4 = 217.5 (for 1 Na)Therefore: TiCl4 is in excess. 211mol compared to 217.5 mol