Ammonia acts as the Lewis base in this reaction by donating its lone pair of electrons, whilst Cu2+ (which is an electron deficient, electrophile) accepts the lone pair of electrons from the ammonia, making it a Lewis acid. The bond between Cu2+ and NH3 is a coordinate bond (also known as a dative bond), whereby the electrons in the bond are both donated by one species (in this case NH3). Thus NH3 is a ligand. Cu2+ is the electrophile (electron deficient) and NH3 is the nucleophile (electron rich).